Additional study material to accompany
Analytical Biochemistry Fall 2004


Updated December 2, 2004
INDEX:

UV-visible spectroscopy
Cell disruption and protein purification
Antibodies
Electrophoresis
Protein mass spectrometry
DNA
Cloning strategies examples from the literature
Polymerase chain reaction
Fluorescence spectroscopy
Radioactivity methods
Centrifugation


UV-visible spectroscopy:

[UV-Visible absorption spectroscopy, a tutorial from Sheffield-Hallam University, Sheffield, UK]
[The electromagnetic spectrum]
[Why is the sky blue? Rayleigh scattering!]
[The Beer-Lambert Law]
[Deuterium Lamp]
[Diffraction Grating]
[Light detectors: Photomultipliers and photodidodes]
[Choosing the Detector for your Unique Light Sensing Application]: a comparison paper from Perkin-Elmer Corp.
[Diode-array spectrophotometer]
[An example of the application of optical difference spectroscopy to the study of enzymes]


Cell disruption and Protein purification:
[Breaking Up Isn't Hard To Do: A cacophony of sonicators, cell bombs, and grinders], from The Scientist
[Ultrasonic homogenizers]
and [Mechanical tissue grinders]
The [Protein Purification Handbook] (large .pdf file) from [Amersham Biosciences]
[HiLoad gel filtration columns from Pharmacia]
[Sephadex G25 for desalting and gel-filtration]
[Calibrating a gel filtration column]
[Packing spheres: Kepler's conjecture]
[Ion exchange chromatography on Sephadex]

Antibodies:
Rockland Immunochemicals for Research
[Mike's Immunoglobulin Structure/Function External Links Page]
[The home page for the textbook Immunology, by J. Kuby]
[Formation of precipitin complexes]

Electrophoresis:
Arne Tiselius, father of electrophoresis; Nobel Prize in Chemistry, 1948.
[Introduction to Electrophoresis]: from the Cell Biology Laboratory Manual
Gustavus Adolphus College, St. Peter, MN, USA.
[Detailed instruction manual for 2-D Gels from Amersham-Pharmacia]
[Take a look at a 2-D protein gel] from the [Swiss-Prot 2D-PAGE database]
[The Electrophoresis Society]: an international organization founded to improve and promote technologies necessary for biomolecular separation and detection.

Protein Mass spectrometry:
[Nobel Prize in Chemistry - for their development of soft desorption ionisation methods for mass spectrometric analyses of biological macromolecules]
[Mass Spectrometry Links and Resources]
[A review article on MALDI MS of proteins]
A good introduction to [MALDI-TOF MS]
and a [review on electrospray MS of proteins]
Electrospray : Principles and Practice (review article from J. Mass Spectr.)
[Protein sequencing by mass spectrometry]
[DNA sequencing by mass spectrometry]
[Guelph gets its own MALDI-TOF MS instrument]
DNA:
[Restriction enzyme database]
[T4 Polynucleotide Kinase]
[Southern blotting] A schematic diagram (used in the lecture)
[Southern blotting] A detailed lab. protocol; Department of Human and Clinical Genetics, Leiden University Medical Center, Netherlands
[Northern blotting] A detailed lab. protocol; Univ. Gesamthochschule Kassel, Germany
[Example of a Southern blot]
[Example of a Northern blot]
[Using an RFLP to trace the sickle-cell gene in a pedigree]
[DNA fingerprinting with RFLPs]
[cDNA synthesis methods] A page from the University of Durham, U.K.
[Exons and introns: split genes: The Nobel Prize in Physiology or Medicine, 1993]
[Cloning vector database]
[LacZ -Complementation and E. coli cloning systems] A page from the Department of Biology at U.C. Santa Cruz
[Plasmid and phage vectors - introduction] A page from Oklahoma State University
[Prokaryotic Expression Vectors] A page from the Institute of Molecular Biophysics, Florida State University
[Plasmid vectors] (Stratagene Corp.)
[Cloning vectors] A page from the University of Mississippi
[Slide show on cloning methods] A page from McGill University
[RT-PCR] an animation

Cloning strategies: examples from the literature
Screening by hybridization to a probe designed on the basis of a peptide sequence
Screening an expression library with an antibody
Selection of clones by complementation of biological function
Positional cloning
Cloning by identification of sequences in GenBank database

[Dideoxy DNA Sequencing]
[DNA sequencing with dye primers or "dye-deoxy" terminators]
[Mapping and Sequencing the Human Genome] a WWW page at the Human Genome Project
[Paul Berg, Walter Gilbert, and Frederick Sanger, The Nobel Prize in Chemistry 1980]

Polymerase Chain Reaction:
[The polymerase chain reaction]
[A nice animated cartoon of the PCR process]
[The Polymerase Chain Reaction (PCR) Jump Station: The ultimate Web page
for information and links on all aspects of PCR]
[Kary B. Mullis and Michael Smith, The Nobel Prize in Chemistry 1993]

Fluorescence spectroscopy:
[An interactive Jablonski diagram]
[Quantitative fluorometry]
[Fluorescence spectroscopy of biosystems]
[Stopped-flow apparatus]
[Fluorescence resonance energy transfer]

Radioactivity methods:
[Liquid scintillation counting] - a comprehensive and informative set of pages about LSC, prepared for a course at UCLA - highly recommended.
[Radioisotopes]: a comprehensive intro. from Texas A&M University; decay modes and kinetics, scintillation counting, etc.
[Nuclear chemistry] (from the "Virtual University North")
Isotopes: [The band of stability]
[Neutrino Physics] (from Duke Univ.)
[Radiation Units]: Curie, Roentgen, Rad, Rem, Becquerel, Gray, and Sievert;
(from the Oak Ridges Associated Universities.)
[ICN Radiochemicals]: a commercial supplier of radiolabelled compounds.
[Liquid scintillation counting] - another nice introduction, from Dept. of Chemistry and Physics at The Nottingham Trent University, U.K.;
this covers everything we will discuss in class, and more.

Centrifugation:
[Centrifugation] - a detailed Web page from Texas A&M: OK for an introduction ...
[Archimedes' Principle] (in case you have forgotten it!) and the wonderful (if apocryphal) story of its [discovery].
Theodor Svedberg, the inventor of the ultracentrifuge; Nobel Prize in Chemistry, 1926.
[Sorvall Centrifuges]
[National Analytical Ultracentrifugation Facility at the University of Connecticut]
["Centrifuge Improvements Put New Spin On A Laboratory Workhorse" (from: The Scientist 9[5]:18, Mar. 06, 1995)]
[Spinning with Dave: David Yphantis's contributions to ultracentrifugation, Correia et al., Biophys Chem. 108: 23-42, 2004]
[The CENTRIFUGE HELPER page calculates relative centrifugal force]
[Density Gradient Centrifugation]
[Density gradient media] (Amersham)
[Density gradient centrifugation] (Axis-Shield; click on "Techniques" to see many specific density-gradient applications)
[Meselson-Stahl experiment (Semiconservative replication of DNA)]
["Biotech And Drug Industry Interest Fueling The Centrifuge Revolution"]; article from "The Scientist", 1996
[Stokes' Law] Univ. of Virginia
[Sucrose density gradient: Example: application to study protein oligomerization]
[The Determination of Molecular Weights by Sedimentation Equilibrium] (Beckman)
[Sedimentation equilibrium: Example: application to determination of protein MW]