Semi-conductors are materials with an electrical conductivity that increases with increasing temperature, a trend that is opposite to that of metals. Semi-conductors characteristically have a band gap between the valence and conduction bands that is smaller than that found in the insulators. The reason the conductivity increases is because as the temperature increases more electrons become thermally excited and are able to jump the band gap between the valence and conduction band. An example of this is silicon. A diagram of the band structure for a semi-conductor is found below.

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